- Title
- The effects of oxygen and metal oxide catalysts on the reduction reaction of NO with lignite char during combustion flue gas cleaning
- Creator
- Yang, Ning; Yu, Jiang-long; Dou, Jin-xiao; Tahmasebi, Arash; Song, Hui; Moghtaderi, Behdad; Lucas, John; Wall, Terry
- Relation
- ARC.LP160100540 http://purl.org/au-research/grants/arc/LP160100540
- Relation
- Fuel Processing Technology Vol. 152, Issue November 2016, p. 102-107
- Publisher Link
- http://dx.doi.org/10.1016/j.fuproc.2016.06.010
- Publisher
- Elsevier
- Resource Type
- journal article
- Date
- 2016
- Description
- The development of lignite-char-supported metal oxide catalyst for reduction of nitric oxide (NO) is investigated in this paper. The characteristics of NO reduction by copper and iron oxide catalysts supported on activated lignite chars (ALC) was studied using a fixed-bed reactor at 300 °C. The results showed that the impregnation of Cu on ALC resulted in higher catalytic reactivity during NO reduction compared with that of Fe. Chemisorption of O₂ and NO on Cu/ALC catalyst was found to play an important role in denitrification. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analyses showed that chemically adsorbed oxygen facilitates the formation of C(O) complex and oxidation of Cu⁰ to Cu⁺ for Cu/ALC catalyst. The C(O) intermediates and C* production formed due to the fact that C/O₂ reaction promoted the reduction of NO. It is suggested that the catalytic reaction of NO in this case comprised of C/O₂ reaction, C(O)/NO reaction and formation of N₂ and CO₂. Cu seemed to have significantly promoted the C(O) formation and CO oxidation compared with Fe. The catalytic reactivity of Cu species for C(O) formation and CO oxidation followed the order of Cu⁰ > Cu⁺ > Cu²⁺. Fe₃O₄ was believed to be the active phase in Fe catalyst. The oxygen and char-supported metal catalysts significantly promoted C/NO reaction, and therefore may lead to a lower operation temperature of NOₓ removal.
- Subject
- catalytic NO reduction; flue gas cleaning; NOₓ emission; activated-char
- Identifier
- http://hdl.handle.net/1959.13/1341094
- Identifier
- uon:28659
- Identifier
- ISSN:0378-3820
- Language
- eng
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